CO2 Utilization in Manufacturing and Agriculture
Carbon dioxide (CO2), often viewed primarily as a greenhouse gas, has numerous valuable applications across various industries. This chapter explores how CO2 is utilized in the manufacture of chemicals, concrete, and plastics, as well as its role as a growth enhancer in agriculture.

Chemical Manufacturing
CO2 serves as an important feedstock in the chemical industry, contributing to the production of several key compounds:
1. Methanol Production:
CO2 is combined with hydrogen to produce methanol, a versatile chemical used in fuels, solvents, and as a precursor for other chemicals. This process offers a more sustainable alternative to traditional methanol production from fossil fuels.
2. Urea Synthesis:
CO2 reacts with ammonia to produce urea, a crucial component in fertilizers and various industrial applications. This process utilizes large quantities of CO2, making it a significant pathway for carbon utilization.
3. Salicylic Acid:
CO2 is used in the production of salicylic acid, a precursor to aspirin and other pharmaceuticals.
4. Cyclic Carbonates:
These compounds, used in polymers and as solvents, can be synthesized using CO2 as a raw material.
Concrete Production
The concrete industry is exploring innovative ways to incorporate CO2, potentially transforming a major source of emissions into a carbon sink:
1. CO2 Curing:
Injecting CO2 during the concrete curing process can accelerate hardening and improving strength. This technique can sequester CO2 permanently in the concrete structure.
2. CO2 Mineralization:
CO2 can be used to carbonate recycled concrete aggregates, enhancing their properties and storing carbon.
3. Alternative Binders:
Research is ongoing into MgO-based binders that can absorb CO2 during the setting process.
However, it's important to note that the net CO2 benefit of these processes can vary. Recent studies suggest that in some cases, the CO2 emissions from capture, transport, and utilization may outweigh the sequestration benefits, highlighting the need for continued research and optimization [2].
Plastics Manufacturing
CO2 is emerging as a promising alternative feedstock for plastic production, potentially reducing reliance on fossil fuels:
1. Polyols for Polyurethane:
Companies like Covestro and Econic are producing polyols from CO2, which are used in polyurethane foams for mattresses, insulation, and other applications. These CO2-based polyols can comprise up to 20% of the final product, reducing the carbon footprint of polyurethane production.
2. Polycarbonates:
Researchers have developed methods to produce polycarbonates using CO2 and plant-based sugars, offering a safer alternative to traditional production methods involving toxic chemicals.
3. Ethylene Production:
Ongoing research aims to produce ethylene, a key precursor for many plastics, directly from CO2 using advanced catalysts and renewable electricity.
4. Polyacrylamide:
Scientists have successfully synthesized polyacrylamide from CO2, demonstrating the potential for producing various polymer types from this greenhouse gas.
While these technologies show promise, many are still in the research or early commercialization stages. Scaling up production and ensuring cost-competitiveness with traditional fossil-based plastics remain significant challenges [3].
Agriculture: CO2 as a Growth Enhancer
In agriculture, CO2 plays an important role in enhancing crop growth, particularly in controlled environments:
1. Greenhouse CO2 Enrichment:
Elevating CO2 levels in greenhouses can significantly boost plant growth and crop yields by enhancing photosynthesis. Optimal CO2 concentrations can increase productivity by 20-30% for many crop species.
2. CO2 Fertilization:
In open-field agriculture, localized CO2 enrichment near crops can stimulate growth, although this technique is less common due to practical challenges.
3. Algae Cultivation:
CO2 is essential for the growth of algae in biofuel production and other applications, offering a way to recycle industrial CO2 emissions.
4. Integrated Systems:
Innovative approaches are being developed to capture CO2 from bioenergy systems and use it directly in greenhouses, creating a closed-loop "plant to plant" system [4].
While CO2 enrichment can boost crop yields, it's important to consider the broader environmental impacts and ensure that the CO2 used is captured from industrial sources rather than produced specifically for this purpose.
In conclusion, the utilization of CO2 in manufacturing and agriculture offers promising pathways for reducing greenhouse gas emissions while creating valuable products. However, continued research and development are necessary to optimize these processes, ensure their overall environmental benefit, and scale them to make a significant impact on global CO2 emissions.